Effect of Extreme Arctic Cold on Materials: Encyclopedia Arctica 2b: Electrical and Mechanical Engineering

Author Stefansson, Vilhjalmur, 1879-1962

Effect of Extreme Arctic Cold on Materials

EA-I. (P . ^ almer^ W. Roberts)

EFFECTS OF EXTREME COLD ON MATERIALS

TABLE OF CONTENTS

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Page
Water 1
Antifreeze Solutions 2
Fuels and Lubricants 5
Rubber-like Material 6
Plastics 7
Glass Materials 15
Fabrics 15
Leather 16
Concrete 16
Icecrete 19
Snowcrete 20
Explosives 21
Wood 22
Metals 26
Steel 27
Precautions for Equipment 29
Preparation of Equipment Specifications 32
Bibliography 34

EA-I. Roberts: Effects of Extreme Cold on Materials

LIST OF FIGURES

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Page
Fig. 1. Flow of coolant which carries heat from engine to radiator 2-a
Fig. 2. Relation between concentrations and freezing protections of various antifreeze solutions 3-a
Fig. 3. Effect of temperature on the compression strength of concrete during the curing period 18-a
Fig. 4. Strength, temperature, moisture relationships from Kollmann’s report 23-a

EA-I. (P . ^ almer^ W. Roberts) ^^

EFFECTS OF EXTREME COLD ON MATERIALS
An understanding of the effect of extreme cold on the elasticity, durability, strength, and other physical characteristics of materials, and the treatment that these materials should receive when exposed to such temperatures is important. Where applicable and when required, information on this subject can be obtained from manufacturers furnishing material or equipment, and from qualified research laboratories.
Water
Fresh Water . Under usual conditions, fresh water freezes at a tempera– ture of 32°F., forming solid ice and expanding about 9% in volume. It takes 80 calories to raise a cubic centimeter of ice across the freezing point and more to bring it to a temperature at which it is potable. Water weighs 62.5 lb. per cubic foot and ice at 32°F. weighs 57.5 lb. per cubic foot. The strength of ice is dependent on its structure (see “Strength and Uses of Fresh-and Salt-Water Ice.”) Trautwin d ^ e^ states that the expansive force of ice is probably ^^ not less than 30,000 per square inch. This force exceeds the yield strength of cast iron (25,000 ^ +^ p.s.i.). Fresh-water ice is 2 to 3 times stronger than sea (salt) water ice. Pressure applied to ice causes momentary melting at the point of pressure, producing a film of moisture. This is especially true at temperatures near 32°F. At progressively lower temperatures, melting due

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to pressure decreases to the vanishing point.
Sea (salt) water freezes at approximately 28.6°F., depending on salinity. Water with a higher salt content freezes at lower temperatures. Newly formed sea-water ice is mushy because of high salinity; at lower temperatures later, when some of its ^ the^ salt has become eliminated, it is flexible as compared to ^^ fresh-water ice. Old sea-water ice is usually stronger than new sea ice, is darker in color, and lighter in weight. So long as it contains appreciable salt it has a rough surface.
Antifreeze Solutions
Approximately two-thirds of the energy in the gasoline used in operating an automobile engine is converted into heat. It is, therefore, necessary to provide special cooling facilities to prevent the metal parts from reaching excessive temperatures. The method generally used is an indirect one in– volving the transfer of heat from the engine to [: ] ^ a^ liquid, usually water, and ^^ ^ Fig. 1^ then cooling the liquid by air through the use of a radiator (see Fig. 1).
Water was naturally selected as a cooling medium because of its availability and relatively high heat transfer properties. However, water has certain short– comings, the most important of which are its high freezing point and its corrosive action on metal parts of the cooling system, which may result in rust clogging and metal perforation. These two major disadvantages are largely overcome by adding materials to the water to prevent freezing in winter, and special chemical ingredients to inhibit corrosion. Oils, sug e ^ a^ rs, and inorganic ^^ salt solutions are generally regarded as unsatisfactory antifreeze materials. In the United States and Canada, approximately one-third of the cars requiring antifreeze are protected with ethylene glycol (glycol) base products and most
Fig. 1 — Flow of Coolant Which Carries Heat From Engine to Radiator

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of the remaining two-thirds employ methyl alcohol (methanol) or ethyl alcohol (ethanol) type solutions. In the Arctic, ethylene glycol base products are used almost entirely.
The antifreeze effectiveness of methyl and ethyl alcohols and ethylene glycol types is shown in Figure 2. These curves bring out several facts. First, the methyl alcohol type give the greatest freezing protection per unit volume, followed by ethylene glycol, and then the ethyl alcohol. Second, all three liquids are capable of depressing the freezing point of water to the lowest atmospheric temperatures likely to be encountered. The first reason is based only on freezing protection per gallon, and does not take into con– sideration the extra quantities of the low-boiling-point alcohol antifreeze solutions required after the initial filling because of boil-away losses, or the superiority of the comparatively high boiling point of ethylene glycol solution in preventing such losses. For antifreeze solutions protecting down to −20°F., the boiling point of the ethylene glycol solution is 22 8 ^ 3^ °F. ^^ while the boiling point of the alcohol-base solution is 180°F.
Unlike water, antifreeze solutions do not solidify when exposed to temperatures slightly below their freezing points but instead tend to form slush. The minimum temperatures to which solutions of the three types of antifreeze having a freezing point of 0°F. may be exposed without giving rise to overheating or other difficulties immediately after the engine is started are: methyl alcohol, −2.5° to −5.5°F.; ethyl alcohol, −5.5° to −8.0°F.; ethylene glycol, −8.0° to −11.5°F.
The lower the freezing point of the antifreeze solutions used, the further below this freezing temperature is it possible to expose the solution without fear of overheating, resulting from circulation restricted by ice crystals of ^^
Fig. 2 — Relation Between Concentrations and Freezing Protections of Various Antifreeze Solutions

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or slush ice, after the engine started. From Figure 2 it is noted that antifreeze protection can be determined in volume per cent concentration in water and easily reduced to pints per gallon of solution (see Table I).

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Table I. Pints of Antifreeze per Gallon Soulution s for Protection ^^ down to Various Temperatures.
Protection to, °F. Methyl alcohol Ethyl alcohol Ethylene glycol
^ +^ 10 1 3/4 2 1/4 2
0 2 1/4 3 2 3/4
−10 2 1/2 3 3/4 3 1/4
20 −20 3 4 3 1/2 ^^
−30 3 1/4 4 1/2 4
−40 3 3/4 5 1/4 4 1/4
−50 4 5 3/4 4 1/2
In the case of ethylene glycol, the greatest freezing protection that can be obtained is −62°F. which is given by a solution containing 60% anti– freeze and 40% water. Solutions containing more than 60% ethylene glycol give less protection.
Glycerim (glycerol) is one of the acceptable nonvolatile antifreeze materials, but because of its relatively high cost compared to ethylene glycol, and its many other important commercial uses, it is not used to any great extent.
Kerosene, freezing point −60°F., had been used in standard automotive cooling systems in localities with extreme cold climates. Its heat capacity is approximately one-half that of water, but automobiles operating with kerosene as a coolant are subject to overheating in warm weather. Additional disadvantages are its unpleasant odor, flammability, and severe action on rubber hose.

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Care should be taken to select an antifreeze containing heavy-duty inhibitors. Two general types are in general use: soluble oils and salts. The oil types are considered generally to be the most satisfactory. Vehicle radiators filled with antifreeze should be tagged showing type of antifreeze.
Fuels and Lubricants
During World War II, special fuels and lubricants were developed to overcome the difficulties in star g ^ t^ ing gasoline and diesel engines previously ^^ encountered in the Arctic. (See “Petroleum Products for Arctic Winter Use in Automotive Equipment” and “Tractor-Type Transportation Units for Arctic Operations” for details on the improvements made on the various properties of fuels and lubricants for low-temperature use.)
In shipping fuels in drums it is important that only extra heavy export– type drums be used. This is necessary as this type drum can be handled easier in the cold and facilitates roping for dropping by parachute from planes. The smooth drum is slippery when wet or covered with ice or snow and it is difficult to rope and attach to a parachute.
The recommendations of the manufacturer of any equipment should be consulted regarding lubrication under cold conditions. Many excellent lubricants have been developed and used successfully in northern operations. However, it must be realized that at extreme temperatures oils and greases become stiff. If an engine has been shut down for any period of time the lubricant may have become so stiff that a fully charged battery will not turn the engine over. This situation may be further aggravated because at such temperature batteries lose much of their energy.

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Rubber-like Material
The general effect of reduced temperatures is the same for all rubber-like materials. As the temperature is decreased the rubber passes from a soft (easily deformed) and elastic state to a more rigid state and finally to a brittle glasslike condition. The various commercial rubbers differ appreciably as to the temperature ranges in which they pass through these various states. None of the available commercial rubbers are truly elastic at extremely low temperatures (below −40°F.). New rubber products stand up better under cold conditions than old rubber. The effect of temperature on rubber materials is predominantly physical and any chemical changes which may take place can, on a practical basis, be ignored.
Some new natural rubber materials are usable at low temperatures approaching −50°F. but in the course of their use it is imperative that they be not subjected to any force at an excessive velocity. That is, rapid bending or flexing at or near such low temperatures will result in breaking or even shattering of the rubber part. For example, rubber tires will develop flat spots at low temperatures. The tread of old rubber tires will chip due to cold embittlement when subjected to force or flexing. New tires show less tendency to crack than do tires of old rubber.
Lower-temperature rubber-like materials are made by specifically compounding the integral parts for low-temperature service. Two general classes of these have been developed: normal natural rubber material to operate (with care) down to −40°F., and special rubber-like material (natural rubber and butyl rubber) for extreme low temperatures to −70°F. Many of the large rubber and chemical companies that specialize in rubber and synthetic rubber products are working on the problem of providing rubber-like materials for use under extreme cold conditions.

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Plastics
Most plastics contain a base material, the properties of which have been modified by the incorporation of plasticizers or fillers. Each base material is the foundation for a group of compositions related in general behavior but differing from one another in individual physical properties. Such basic groups of plastics are: acrylics, celluloses, nylons, ethylene , polymers, ^^ vinyl ester polymers, polyvinyl acetals, phenolics, urea resins, caseins, alkyds, neoprene, etc. groups which contain several different compositions are subdivided into types. Each type represents one or more compositions, each of which is designed to give superior value of some specific property even at the expense of some other property. There is, for example, Type L ^ I^ , ^^ g ^ e^ neral; Type II, temperature resistant; Type III, impact resistant; Type IV, ^^ moisture resistant; etc. Where further subdivision is required, the types are subdivided into grades. Each grade represents, at broadest, a very restricted number of common commercial materials which are quite similar both chemically and physically. These groups, types, and grades usually correspond to those given in the specifications of the American Society for Testing Materials.
The service success of an article of any plastic often depends as much upon the design and fabrication processes as on the material itself. The importance of selecting items of good workmanship in both design and fabrica– tion for cold-weather operations cannot be overemphasized. The plastics industry has developed a background of practical experience in design, fabrication, and testing of plastics, and should be consulted regarding specific cold-weather problems. The importance of selecting the proper material and consulting with plastic manufacturers concerning cold-weather

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problems cannot be overstressed. It is important not only to select the proper material but to use it properly in the field. Too frequently, good plastics improperly handled in the field failed, when the same material properly utilized would have been entirely satisfactory.
As an aid in understanding this field of material, a list of the more important plastics by resin group and subgroup, trade names, available forms, and commercial uses is given in Table I. (The code for the available forms is: F, filaments; M, molded; R, rods; S, sheeting; T, tubing.) where applicable, comments on the effects of extreme temperatures and care in use in the field are given in the text.
The acrylics are perfectly clear and transparent. They have the best resistance of all transparent plastics to sunlight and outdoor weathering, and will tolerate years of exposure without significant loss of properties. They possess a good combination of flexibility with shatter resistance and rigidity. Their impact strength is lower than the celluloses, but the effect of extreme low temperatures upon this property is much less pronounced; hence, articles designed for use at ordinary temperatures will not show excessive embrittlement at −50°F.
Cellulose nitrate is the toughest of all thermoplastics. It has low water absorption and is resistant to mild acids. At −50°F., its impact strength is about 35% of its impact strength at normal temperatures (77°F.). Cellulose nitrate is very flammable; it is not suitable for prolonged service in outdoor sunlight for it turns yellow and becomes brittle.
Cellulose acetate is comparatively tough. Its low temperature impact strength and embrittlement characteristics are inferior to those of cellulose

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Table I. Some Important Commercial Plastics^.^ ^^
Resin group and subgroup Trade names Forms available Uses
Acrylics: Methyl methacrylate resin Lucite Plexiglas M, R, S, T M, R, S Windshields, goggles, dentures, artificial eyes, drafting in– struments, automotive parts, aircraft enclosures
Celluloses: Cellulose nitrate Celluloid Nitron Nixon C/N Pyralin R, S, T, F R, S, T R, S, T R, S, T Fountain pens and pencils, drawing instruments, spectacle frames, bottle caps, toilet seats, tool handles, shoelace tips, film
Cellulose acetate Fibestos Lumarith Nixon C/A Plastocele R, S, T R, S, T, M R, S, T, M R, S, T Containers, luggage, food cases, truck curtains
Chemaco Hercules Koppers Tenite I M M M M Knobs, goggle frames, combs, brushes, tool handles, safety goggles, eye shields, automotive parts and housings
Cellulose acetate butyrate Tenite II M Telephones, steering wheels, film spools, radio housings, knobs and pulls, light supports, coil spools, brush backs
Ethyl Cellulose Celcon Chemaco Ethocel Hercules Koppers Nixon E/C M M M, S M M M, S Radio housings, toothbrushes, pen and pencil barrels, tool handles, knobs and pulls, flashlight cases
Nylon: Textile filament types F Textile fiber, ropes, lines, hose, tents, stockings, clothing, bristles, surgical sutures
Injection, extrusion and alcohol-soluble types M, S Injection and compressed molding, covering for wire and sheets, solution castings, small bearings, specialty containers, electrical coil forms and insulators, small gears, cams, coatings

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Table I. Some Important Commercial Plastics (contd).
Resin group and subgroup Trade names Forms available Uses
Ethylene plymers: Polyethylene Polythene F, M, S, T ^ F, M, S, T^ Films, liners, closures, wrappings for frozen food, primary cable, ^^ insulating material, coating for weatherproof wire
Polytetrafluoro– ethylene Teflon M, R, S, T Films, tubes, tapes and special applications made by rolling, drawing, or machining
Polyvinyl acetals: Polyvinyl formal Formvar M Insulating enamel, base for electric wires, phonograph records
Polyvinyl butyral Butacite Saflex Vinylite M, S S M, S Plastic interlayer, laminated for safety glass, sheeting, and coatings for dustproof and waterproofing fabrics
Vinyl ester polymers: Polyvinyl chloride Geon Marvinol Pliovic Ultron Vinylite M, S M M, S M, S M, S Jacketing material on electric wires and cables, water-repellent garments, shower curtains, garment bags, upholstery, belts, floor coverings, overlays for maps, phonograph records
Polyvinylidene resins: Finylidene chloride Saran F, M, T Hoses, flexible tubing, rigid pipe, lined steel pipe, moisture-resistant films and fabrics for upholstery and transportation seating
Polystyrene Bakelite Cerex Chemaco Koppers Loalex Loalin Lustrex Styron M M M M M M M M Standoff insulators, antenna in– sulators, radio coil forms, telephone equipment, fluorescent light fixtures, wall til s ^ e^ , combs, ^^ knobs and pulls, shaver housings, camera cases, refrigerator parts, bottle caps
Polystrene expanded Styrofoam S Insulating material in refrigera– tion construction, buoyancy agent for life rafts and small metal boats

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Table I. Some Important Commercial Plastics (contd).
Resin group and subgroup Trade names Forms available Uses
Phenolics: Phenol-formaldehyde resin Bakelite Durez Durite Resinox M M M M Camera cases, photographic film spools, handles, instruments, boxes, radio cabinets, ignition parts, instrument panels, pulleys, housings, terminal blocks, telephone parts, goggle frames, wheels
Melamine resin: Melamine-formalde– hyde Melmac Plaskon Resimene M M M Compression moldings, electrical fittings, sockets, food containers
Urea resins: Urea-formaldehyde Beetle Plaskon M M Buttons, tableware, boxes, electrical parts and lighting reflectors
Synthetic rubber: Chlorobutadiene Neoprene M, S, T Hose, molded parts, weather strip– ping, wire and cable jacketing adhesive, coated fabric, electrical cable construction, inflatable gear, sealing strips
nitrate. Cellulose acetate is superior to cellulose nitrate in resistance to outdoor exposure and to burning. Sunlight has little effect on this material. Since there are many commercial compositions of this material, it is advisable for a given application to indicate the application and desired properties, for example, for general use, resistance to heat, cold, impact, or moisture.
Cellulose acetate butyrate material is tough and has dimensional stability. Fluctuation in dimension must be considered when articles are made of a com– bination of this material and glass or metal.

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Ethyl cellulose material possesses toughness, high impact strength at low temperatures, and excellent dimensional stability. When the article is in combination with glass or steel, assurance must be made that the wall thickness of the plastic is sufficient to withstand the strain caused by temperature changes. Type II of this plastic is specifically designed for low-temperature resistance. At −50°F., its impact strength is about 40% of its impact strength at normal temperatures.
Nylon is a generic term for any long-chain synthetic polymeric amide which has recurring amide groups as an intergral part of the main polymer chain, and which is capable of being formed into a filament whose structural elements are oriented in the direction of the axis. Nylon textile filament materials are noted for their toughness. The effect of extreme cold on the mechanical properties of cords and ropes is small: tensile strength increases and elongation decreases. Woven fabrics will not be stiffened or embrittled by extreme cold and remains soft and pliable at −40°F. The effect of prolonged exposure to sunlight and outdoor weather is not enough to impair practical utility.
Several different types of nylon g plastic ^ s^ are involved here and their ^^ ^^ properties are not identical. Impact strength is measurably decreased by ex– treme cold but toughness and impact strength at low temperatures are still so good that nylon plastics have been successfully used at low temperatures. At −40°F., the impact strength of nylon is about 55% of its impact strength at normal temperatures. The electrical properties of nylon plastics are better at low temperatures than at normal temperatures. Prolonged exposure of nylon plastics to sunshine and weathering is not recommended.
Polyethylene and polythene materials are tough and durable. Their toughness is not seriously effected by low temperatures. These materials

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remain fairly flexible at moderately low temperatures, stiffen slightly at temperatures of −30°F. and lower, and become brittle at −94°F. They have excellent electrical properties, extremely low moisture vapor transfer qualities, resist solvents and strong acids, and have other desirable qualities such as nontoxicity. / ^^
Polytetrafluoroethylene has potential utility owing to its excellent thermal stability, resistance to corrosive reagents, and low dielectric loss. It is not embrittled by extremely low temperatures. Films can be flexed at temperatures as low as −148°F. without breaking. Its resistance to outdoor weathering is excellent.
Polyvinyl acetal material provides a tough impact-resistant adhesive layer for safety glass over a wide range of temperatures down to about −40°F., is stable to light and heat, relatively insensitive to moisture, and has good adhesive qualities. It is an excellent thermoplastic adhesive for leather, rubber, paper, wood, canvas, laminated cellophane, and glass. It is also excellent for coating fabrics for raincoats, water-repellent garments, tentage, food and clothing bags, etc.
Polyvinyl chloride compositions are noteworthy for their heat resistance, exceptional toughness, and ability to withstand continued exposure to maximum temperature differences. Some of these compounds have a low-temperature brittleness approaching −40° and −50°F. when subjected to bending. However, such material if subjected to sudden shock would fail at higher temperatures, possibly approaching −30°F.
Vinylidene chloride material is tough, resistant to chemicals and prolonged immersion in water, nonflammable, and useful over a wide range of temperatures.

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Polystyrene has good electrical properties, good resistance to acids and solvents, excellent dimensional stability, low unit weight, and general stability satisfactory at extreme low arctic temperatures (below −50°F.). Many of the materials have good outdoor weathering properties.
Polystyrene Expanded . One outstanding property of this material is its low thermal conductivity (0.27 B.t.u. per hour per sq.ft. per °F. per inch). Another is its low water absorption and moisture transmission rate, which enhances its usage as an insulating material under extremely cold conditions. This material has good structural strength and is easy to handle, it may be bonded to itself, concrete, brick, wood, or metal. It has a minimum buoyancy of 55 lb. per cubic foot.
Phenol-formaldehyde resins are thermosetting and the molded types are shaped and hardened by heat and pressure. They are hard, strong, rigid, and are light in weight. They are not readily flammable, have good electrical insulating properties, but are not suitable for prolonged outdoor exposure as the lighter colors fade and the material may change in water content with resultant slight expansion and contraction. Types are made to provide general– purpose shock and electrical, heat, and chemical resistance. The shock-resistant types show best combination of flexual and tensile strength at extreme low temperatures. The cast phenolic-type resins are not recommended for outdoor use. The laminated phenolic products include some of the strongest materials in the plastic field.
Melamine-formaldehyde resins are thermosetting, rigid, posses a hard surface which resists wear, have good electrical properties, and water absorption is low. These materials have good dimensional stability plus good strength and shock resistance. The laminated melamine products are used widely for elec– trical instrument panels.

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The urea-formaldehyde resins are of the thermosetting type. They possess a high degree of translucency and offer unlimited color possibilities. They have good mechanical and electrical properties. They have been widely used within a temperature range of −70° to 170°F.
All neoprene products when exposed to temperatures in the range of 0° to −50°F. will stiffen and lose some of their flexibility and resiliency. However, by proper compounding of neoprene, it is possible to make compositions that retain sufficient flexibility to be practical in the range of −50° to −60°F.
Glass Materials
Ceramics are not ordinarily effected by extreme cold temperatures. How– ever, a warm blast of air or a sudden change of temperature may cause frozen material to shatter.
Window glass does not show any visible reaction to cold. Thin sections are susceptible to sudden changes in temperature but they are designed to withstand average thermal shock of 150°F.
Laminated safety glass (plate and sheet) does not show a visible reaction to cold. It is designed to withstand 150°F. average thermal shock and to meet minimum requirement of −65°F.
Structural glass shows no visible reaction to cold. It is designed to withstand average thermal shock of 150°F.
Fabrics
Untreated and water-repellent textiles give satisfactory service down to −40°F. Canvas and heavy materials lose their pliability at low tempera– tures and when frozen h ^ sh^ ould be bent or stretched with caution. Loss of ^^ elasticity should not be mistaken for shrinkage.

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Leather
At low temperatures leather becomes stiff and cracks, often tearing easily. When wet, untreated leather becomes frozen, it will not stand tension, bending, or impact. Leather items that are to be subjected to extreme cold should be carefully tanned and then treated with a light coat of good shoe oil or lard. Tanned skins are less easily injured by wetting and subsequent freezing than untreated skins. Much has been said about the difference between skins scraped and prepared by the Eskimos and those tanned by commercial methods. Commercial-tanned skins weigh more per square unit than Eskimo-prepared ones. Commercial-tanned items tend to stiffen, thereby reducing utility. For clothing, commercial-tanned skins are not as warm as the E [: a]^ s^ kimo-prepared ones. ^^ However, since commercial tanning is cheaper, commercially tanned items are more frequently used. Where leather and fur clothing items are required for midwinter chill occupations, on the trail or away from main encampments, it would be advisable to use clothing made from Eskimo-prepared skins.
Concrete
The problem of the construction engineer in cold areas is similar to that of engineers in more temperate climates, that is, to produce concrete of the quality specified and assumed in design with the materials available. Aggre– gates, meeting requirements as to qualities of hardness and toughness, are usually available but these may be limited in the desired shape, size, and graduation of the particles. The most dependable and readily available natural sources of aggregates are river banks and old terraces, sand and gravel bars, river deltas, and coastal beaches. Due to the handling difficulties imposed by permafrost, the availability of such materials must always be a consideration.

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On all work Portland or high-early-strength cement, meeting the speci– fications of the American Society for Testing Materials, should be used. High-early cements are preferred to the portland as the concrete need not be heated as long in curing. Due to the rough abuse to which containers may be subjected, cement should be double-bagged in heavy durable bags. Where possible bags should be palletized for loading, unloading, and storage. Proper consideration should be given to storage; cements protected from moisture may be kept indefinitely without loss of strength.
Various admixtures are sometimes used in concrete to increase workability, to prevent freezing, to hasten setting, to facilitate curing, to increase watertightness, etc. the use of such admixtures is not ordinarily harmful if carefully and judiciously controlled. Admixtures to prevent freezing con– sist of common salt (NaCl), calcium chloride (CaCl 2 ), or a mixture of these. These admixtures may be used with judgment in moderately cold weather but should not be relied upon to prevent freezing in extremely cold weather or when such weather is expected immediately following the placement of concrete.
Increasing the temperature of concrete in cold weather is commonly accom– plished by heating the aggregates or the water or both. The most readily available item in the Arctic is water which, except during a shot time during the summer, will require heating. The temperatures to which the water must be raised in order to provide the desired temperature for the concrete can be calculated by the formula:

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<formula>T = S ((TaWa + TcWc) + TfWf + TmWm)/(S(Wa + Wc) + Wf + Wm)</formula>
where: T = temperature of concrete (should not be greater than 80°F. for most work)
S = 0.22 (assumed specific heat of dry material)
W a = weight of aggregates (surface dry); T a = temperature of aggregates
W c = weight of cement; T c – temperature of cement
W f = weight of free moisture in aggregates; T f = temperature of free moisture in aggregates
W m = weight of mixing water; T m = temperature of mixing water Mi z ^ x^ ing water is commonly heated in a boiler by live steam o f ^ r^ by heating coils. ^^ ^^ The temperature of the water is usually held between 90° to 120°F. and should not exceed 165°F. because of the danger of causing a flash set of the cement.
Concreting can be successfully accomplished in cold weather without adversely affecting the final quality of the product. The rate of development ^ Fig. 3^ of the strength increment is slow at low temperatures as shown in Figure 3. If actual freezing is prevented during the setting process, and if supports are left in place until the concrete has reached a compressive strength of 1,500 p.s.i., there should be no detrimental effects of the low temperatures on the quality. To do this, it will be necessary to heat the aggregates and water, place and tamp or rod it quickly, and enclose it with tarpaulins or other housing. Heating by air, stoves, or steam will be required during curing, and care should be taken that the concrete does not get too hot. In extreme or severe weather it may be necessary to protect the work in an artificially heated enclosure until the end of the moist curing period to prevent loss of heat to the atmosphere.
Fig. 3. Effect of temperature on the compression strength of concrete during the curing period.

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Special problems arise when concrete is poured against a frozen face or in permafrost. Thaw ensues upon contact with the concrete, and the water produced may initially cause settlement, and later freeze, with the possi– bility of heaving and resultant damage to the structure. In the case of vertical walls being required against a frozen face, precast sections may prove more satisfactory. Slab construction in permafrost requires suitable insulation between the concrete and the permafrost.
Fresh concrete when frozen may be recognized by its white color. Ordinarily, concrete retains its dark slate color in cold weather for several days. Badly frozen concrete may also swell or spall in spots. Concrete that seems to be frozen can be tested by placing it over a stove or by immersion in hot water. If frozen, it will sweat and become soft or crumble; if not frozen, no change will occur.
Concrete that is frozen can be saved by enclosing and heating. After thawing, the concrete will resume its setting from about the point it had reached at the time that it was frozen. Concrete that has frozen after setting has started is damaged to a certain extent due to the mechanical expansion action of the ice crystals. The amount of damage will depend on the degree of setting which has preceded the freezing. It is this action of ice which makes repeated freezing of new concrete crumble and become worthless. The ordinary case of frozen concrete is one in which the concrete is placed at a low temperature and is allowed to freeze before setting action occurs.
Icecrete
Icecrete is a term applied to a material made from aggregates with ice acting as the cementing agent. During the period of no thaw, icecrete is a

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dependable substitute for concrete in the regions of extreme cold. By mixing water and aggregate materials (sand and gravel), either by hand or in a con– crete mixer, a plastic and flowable homogeneous mixture may be made. The mixture may be poured, similar to concrete, into forms and rodded or tamped to assure compaction. Forms may be built from snow or ice blocks, brush, or wood, if available, and may be left in place.
Due to the presence of the aggregates, icecrete is darker in color than ice and will absorb more heat from the sun, which may cause melting. To minimize this action the icecrete structure or mass should be covered with snow, ice, or canvas.
Icecrete is generally tougher than ice, does not crack readily, and is comparatively shatter and impact resistant. This material is excellent for construction of roads, protective barriers, foundations for structures to be used only in winter, deadmen for “tie downs,” and as a substitute for mass concrete construction required during no-thaw periods.
Snowcrete
Snowcrete is a term used to describe snow resulting from compaction by natural or mechanical means. Until recently little work had been done in the field of mechanical compaction of snow; however, natural compacted snow has been used for a long time in the form of snow blocks. Such blocks have been used primarily by Eskimos for the construction of snowhouses, shelters, and windbreaks.
All the properties of compressed snow have not yet been determined by experimental work. The hardness of snow is based on the strength which attaches individual snow particles to each other. The mechanical value of

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compacted snow depends on its density, temperature, and texture. Snow, like soil, must be compacted in thin layers. Snow may be compacted easily and reached its highest density at temperatures approaching 32°F.; snow thus compacted will attain its greatest value of hardness.
One of the notable properties of snow is that, at temperatures below freezing, its hardness continues to increase if left undisturbed after having been compacted. Compaction decreases the thin films of air between crystals and thus increases the density and resultant contact between and growing together of crystals.
The field of snowcrete utilization is being slowly developed. It is apparent that compacted snow may be used in cold weather for temporary buildings, windbreaks, road surfaces, and for air strips.
Explosives
All modern explosives used in the bricks are of the low-freezing variety and are designed to eliminate freezing under ordinary conditions of exposure at any temperature normally encountered. Gelatins and similar type explosives will become quite hard when subjected to low temperatures but will not freeze. Certain high explosives composed of a mixture containing mainly of ammonium ^^ nitrate are absolutely nonfreezing. Correspondence with principal explosives companies indicates that no case of frozen dynamite has been reported in recent years under severe Canadian and Alaskan conditions.
In the event that an explosive is suspected of being frozen, the employment of the simple “pin test” will readily determine whether or not the explosive is frozen. An ordinary pin will not penetrate a frozen column of explosive, but can be inserted quite easily into one that is merely very hard.

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All explosives should be stored and transported in accordance with standard precautions recommended by the manufacturers.
Blasting caps and electrical blasting caps have withstood satisfactory storage at laboratory temperatures as low as −110°F. (−78.9°C.). These tests revealed little or no change in characteristics.
Safety fuses show no appreciable change in performance after storage at extreme low temperatures except that the burning time may be slightly increased. Caution is required in the handling of safety fuses after freezing as the fuse covering, particularly the waterproofing, will crack at low temperatures. It would, therefore, be necessary to uncoil the fuse and prepare the explosive devices at normal temperatures. Primacord detonating fuse will perform satisfactorily at low temperatures, providing it has not been wet previous to freezing. Care must be taken, however, to prevent breaking or cracking. If a detonating fuse becomes wet before freezing, it will be difficult to initiate, and a booster will be required to insure detonation.
Wood
The results of a limited amount of research conducted on various woods and a review of available literature indicate no significant effect on the physical properties of wood due to extreme cold. No special precautions, therefore, need be observed for the use of wood in the very cold climates. Wisconsin white oak has been extensively used for sled runners for heavy-duty arctic sleds. Other wood materials, built for use in more temperate climates, have been widely used in the Arctic without noticeable failure.
Comprehensive investigations into the effects of extreme low temperatures on the strength properties of wood were made in Germany by Franz Kollmann and published at Eberswalde in 1940. Later the Forest Products Laboratory of the

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Forest Service, U.S. Department of Agriculture, reviewed all literature on the effect of arctic exposure conditions on the strength properties of wood and published a report June 4, 1948. Parts of the ^ this^ report are quoted: ^^
“Discussion of Strength Tests
On the basis of the information gathered in the review of available literature and in talking with the individuals mentioned previously, the elimination of low temperature in itself as a probable cause of the trouble seems justifiable. There is general agreement among the various investigators that in most cases strength properties are actually improved by comparatively short-time exposure to below freezing temperatures, a notable exception being impact strength which was found to exhibit little change either way with changes in temperature for wood at 7.5 percent moisture content and at 12 percent in the range from about 75°F. down to −58°F. Whether long-time exposure to low temperature or to fluctuating temperatures such as occur in the Arctic would alter these strength-temperature relationships has not been determined. ^ Fig. 4^ (See Fig. 4.)
Another factor, one that is known to have considerable effect on strength properties, is moisture content. Below the fiber saturation point most strength properties increase with decreasing moisture content, an exception being those properties representing toughness or shock resistance, which usually exhibit little change with changes in moisture content at temperatures above freezing. However, Kollmann found that impact strength of laminated wood in the sub-frozen state is very materially affected by moisture content, but his investigation was made on only one species (not specified) of laminated wood. Since impact strength is such an important property, especially for wood used
^Fig. 4^ STRENGTH, TEMPERATURE, MOISTURE RELATIONSHIPS FROM KOLLMANN’S REPORT

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in containers, the influence of moisture content in the sub-freezing temperature range upon this property should not be overlooked in the preparation of con– tainers for use in Arctic regions.
Observations that were noted in some of the tests but were not elaborated upon concerned the suddenness and cleanness of the breaks exhibited by the frozen specimens. In other words, there seemed to be a tendency for frozen wood, even though somewhat stronger than in the unfrozen state, to break abruptly without warning when the maximum load was exceeded. This may have a bearing on the behavior of hammer handles reported to have failed in service ^ ,^ ^^ presumably due to exposure to extreme cold and the dryness of the atmosphere.
The reports from Alaska describing the failures of certain wood articles to give satisfactory service all mentioned the extreme dryness of the wood in connection with the failures. The moisture content of wood in equilibrium with the surrounding atmosphere is dependent upon the relative humidity of the atmosphere and is practically independent of temperature in the range below about [: ] 70°F. Thus, wood exposed to outdoor winter conditions at Fairbanks, where the relative humidity averages about 83 percent during that season, should attain an equilibrium moisture content of about 17 percent. Therefore, if low moisture content is associated with the failure of wood articles to give satisfactory service, it should not be so likely to occur with those store s ^ d^ ^^ and used outdoors or in unheated sheds. On the other hand, if wood articles are stored in heated buildings they are subjected to conditions that will result in extreme dryness, even less than 1 percent moisture content, if such exposure is continued for sufficient time. For instance, if outdoor air at −24°F. and 83 percent relative humidity is brought indoors and heated to 60°F. without adding any moisture, the resulting relative humidity will be less than

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2 percent and will result in an equilibrium moisture content for wood of about one-half of one percent, or practically even-dry. In fact, air at sub-zero temperatures contains so little water vapor, even at saturation, that regardless of its l relative humidity, when this same air is heated to room temperature without addition of moisture the resulting atmosphere will be capable of drying wood to less than one percent moisture content. This could explain the extreme dryness and brittleness mentioned in connection with the reported failures.
It should be stated here that while most strength properties have been found to improve as temperature and/or moisture content decreases, the tests made to determine this fact were all made on clear straight-grained specimens in which knots, cross grain, shakes and checks were entirely eliminated. In actual practice, however, these defects are often present and their effect is further accentuated by the shrinkage which accompanies drying in the range below the fib [: ] ^ e^ r saturation point. This is especially true in the lower grades of ^^ lumber used for container purposes.
Other properties of wood that are very materially influenced by moisture content are nailing and nail-holding qualities. Dry wood is harder to nail and splits more easily than does green wood. If the wood dries after the nail is driven the nail-holding power is often seriously reduced. Thus, the service– ability of wood articles, such as wooden shipping containers is materially affected by the moisture content or the changes in moisture content of the wood in response to exposure conditions.
In conclusion, it may be stated that the information assembled in this survey fails for the most part to explain the reported reduction in the serviceability of wood articles under Arctic exposure. Lacking specific

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samples of the wood for examination and test, as well as more complete information regarding the history of those articles that failed to give satisfactory service and the frequency of such failures, it is not possible to reach a definite conclusion as to the cause of the trouble at this time.”
Metals
The properties of many metals undergo changes at extreme low temperatures, particularly in strength, toughness, brittleness, and durability. In many of the hard metals an increase in brittleness may result from exposure to extreme cold. Caution must be exercised in selecting metals for service at extreme low temperatures. In the selection of metal parts, attention should be given to composition as well as to the fabrication of the finished metal article. Preventive maintenance, including ^ a^ check of metal fittings and frames susceptible ^^ to extreme shock or impact conditions, is most important during actual field operations.
An important precaution to personnel handling metals under extreme condi– tions, and one that must be carefully followed, is not to contact the metal with unprotected hands or other uncovered parts of the body. The perspiration of the skin affords sufficient moisture to freeze the hand to the metal. Forcibly removing the hand may result in removal of the skin and a possible resultant painful injury. However, the hand must be torn away as quickly as possible, unless there is instantly available a quick-heating means, such as a torch, for the frostbite deepens with lengthened contact. Metal parts that need to be handled frequently, such as the bolt, trigger, and trigger guard of a rifle, should be covered with some such material as adhesive tape and can then be used freely with bare hands.

EA-I. Roberts: Effects of Extreme Cold on Materials

Steel
A few properties of steel such as strength, eleasticity, hardness, brittleness, and magnetism are at their highest point at very low tempera– tures and decrease with temperature rise. However, the resistance of steel to shock decreases very much with lowered temperatures. Certain ordinary carbon and low-alloy-content steels exhibit a loss of toughness when low temperatures near −40°F. are reached, so that some of these steels are too brittle to use in impact service in cold climates.
Stainless Steel . Chromium-nickel types of stainless steels are especially well suited for low-temperature applications because their strengths and toughness properties are improved at extreme low temperatures. Products made from this material are those requiring toughness and resistance to corrosion as parachute fittings, shackles, etc.
Hardenable chromium types show moderate loss of toughness at extreme low temperatures. Sled runners, skates, etc., are made from this material because of its high hardness and corrosion-resistance characteristics. Nonhardenable chromium types show marked loss of toughness at 0°F. and lower. This material is used primarily for parts requiring high resistance to corrosion such as carburetor and fuel nozzles.
Cast Iron . The general term cast iron includes gray irons, pig irons, white cast irons, chilled cast irons, and malleable iron. Cast irons are alloys of iron, carbon, and silicon with the carbon content usually not more than 4.5% or less than 1.7%. Gray irons are the most widely used cast metal and they vary in tensile strength from 20,000 to 60,000 p.s.i. Re– sistance to impact usually increases with increased tensile strength; however, at extreme low temperatures the impact resistance decreases greatly.

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Lead shows no visible or otherwise detectable effects of temperature in the range of temperatures experienced in the Arctic. No special care is re– quired for the maintenance of lead or lead-base alloys such as sheet lead, lead pipes, and lead assemblies or shapes. Babbitted metals (lead-base bear– ing alloys) can be expected to behave in a manner similar to that of various solder alloys.
Solders (lead and tin alloys). Soft or low-strength solders that contain a high percentage of lead (65 to 97.5%) retain their ductility and increase in impact strength at low temperatures. Tin contents up to 15% have no serious embrittling effect. When the percentage of tin becomes as high as 50%, serious embrittlement and decrease in impact strength occur.
The increase in tensile strength of solder alloys and in the breaking load of soldered joints is linear with decreasing temperature. High-strength solders, those containing the most tin (50%), show the greatest increase in tensile strength, and the low-strength solders, those containing the most lead (97.5%), show the least increase in tensile strength as temperatures decrease below freezing.
Breaking loads of soldered copper tubing at low temperatures are nearly independent of the kind of lead-base solder used. Impact strength and ductility of such joints would pro h ^ b^ ably be influenced by low temperatures, ^^ in view of the properties of individual solders.
Copper and Its Alloys . All wrought copper alloys are alike in that the effect of extreme low temperatures is to improve all useful mechanical properties. Hardness, yield strength, and tensile strength show material improvement, and the ductility is better at extreme low temperatures than at room temperatures. Impact properties are practically unaffected. The

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ductility of cold-worked alloys increases to a greater extent than does that of annealed material, and they are, therefore, the logical materials for stressed parts for low-temperature service. Castings of copper alloys show a small decrease in ductility at low temperatures.
Aluminum Alloys. Tests and field use of aluminum and its alloyw^s^ indicate ^^ that they are admirably suited for extreme-low-temperature service. Tests made to subatmospheric temperatures indicate that the tensile, yield, and impact strengths of all aluminum alloys increase at extreme low temperatures. Aluminum alloys retain ductility at these temperatures, corrosion resistance is enhanced, and there is no increase in brittleness. No special precautions regarding methods of handling at extreme low temperatures are required.
Precautions for Equipment
PRECAUTIONS FOR EQUIPMENT
General. All equipment should be winterized for extreme cold prior to winter operations in the Arctic. Problems which must be considered for various types of equipment are: insulation of fuel and hydraulic lines and ignition systems; protection of batteries; change to selected grades of cold-weather lubricants; provide protection for operators; eliminate the possibility of ice forming on the inside of equipment due to “breathing of the equipment”; and the provision for ice grousers on tractor-type units.
Storage Batteries. High acid content batteries give good performance at low temperatures but will deteriorate rapidly at normal temperatures. This should be considered in selecting batteries for arctic operations. On all equipment using batteries, measures must be taken to maintain a reasonable operating temperature for the battery by adopting the following precautions:
  • 1. Install battery in a location away from the hull or frame which is in contact with the outside of^r^ the ground. ^^

    EA-I. Roberts: Effects of Extreme Cold on Materials

  • 2. Insulate batteries with a rock wool, fiber glass, or celotex casing or jacket.
  • 3. Provide heat for battery installation area if necessary. The output of batteries decreases because of increased internal resistance at low tempera– tures. A fully charged storage batta^e^ry at 70°F. will produce only 50% of its ^^ rated capacity at 0°F., 20% at −40°F., and 10% at −60°F.
Batteries should be maintained carefully and hydrometer readings taken regularly because lead-acid batteries falling below a 1.125 reading will burst at 0°F. Storage batteries will not freeze at extreme low temperatures if well charged.
Dry Cell Batteries. The life of such batteries is greatly shortened by use at low temperatures, and lower voltages are developed. Less than 10% rated capacity will be produced by the dry cell at 0°F. Battery cases should be insulated and when not in use carried in warm places. An ordinary flashlight that grows dim, when carried in a mittened hand on a cold day may brighten if warmed by holding ^in^ the bare hand. However, there must be some such thing as thin cloth between the hand and the flashlight to prevent a frost burn. Some northerners slit the palm of one mitten so they can hold the inserted shaft of the flashlight.
Cameras, Optical and Scientific Instruments. All cameras, binoculars, and scientific instruments should be carefully cleaned, reducing the lubricant to a minimum, and should be hermetically sealed or moistureproofed where possible. Such instruments if to be used out of doors should be kept outside during cold weather to eliminate alternate heating and chilling, which will be a source of errors as well as tend to cause internal fogging. In using binoculars, sextants, theodolites, etc., personnel should be warned against

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fogging the lenses by breathing directly onto them or pressing the eye too close to the eyepiece. Lightweight nylon gloves, worn under mittens, are sometimes used by personnel to adjust instruments.
Firearms. Rifles function well at extreme low temperatures, providing a minimum of precautions are taken to protect them. Grease should be wiped from all mechanisms and the barrel cleaned when outside temperatures drop below freezing. Firearms should be kept outside. This point is considered crucial by all experienced arctic riflemen. Weapons should be carefully checked before and after firing to see that no ice or snow has clogged moving parts. A gun cover should be provided for each weapon, and a cap should be used when hunting to cover the muzzle of the rifle to prevent snow entering the barrel. Metal surfaces of the rifle which may be touched by the hand in loading and firing are sometimes covered with tape, permitting use of bare hands. Firearms should be cleaned and oiled with a light gun oil when tempera– tures return to above freezing.
Blasting Machines. The push-down type of blasting machine is preferred for use in cold weather. The machine should be cleaned and oiled lightly with a cold-weather lubricant to obtain the best performance. The blasting galvanometer, used to check electrical circuits, becomes completely inactive at very low temperatures, but is not permanently injured and will function properly if brought back to normal temperature conditions. It is essential for best performance that the galvanometer be kept warm by some means until the time for actual use.
Wire Ropes, Cords, and Strands. These items have been used successfully in exposed operations at extreme cold temperatures both on the ground and in the air. Precautions regarding the use of the wire-rope items will depend largely on the material from which the item is made and the extreme temperature

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to be encountered. Instructions should be obtained from the manufacturer regarding the use of the cable, and the effect of extreme cold on the brittleness, impact strength, metal fatigue, and other properties.
Bolts. Failure^s^ of connectors in structures and equipment have been a ^^ problem. The Chairman of the American Society of Testing Materials Committee on Low-Temperature Bolting advises as follows:
“Only ASTM Specification A 320 bolting, preferably Grade L7 is recommended. This grade meets the impact requirement at −50°F by a wide margin. It is possible that ASTM specification A 261 heat treated carbon steel bolting would be satisfactory, although its impace^t^ resistance would be less, and ^^ therefore this material would be borderline.”
PREPARATION OF EQUIPMENT SPECIFICATIONS
In the outfitting of personnel and organizations who are to engage in operations under extreme cold conditions, it is oftentimes necessary to purchase or design equipment under contract. The preparation of specifications for equipment to be furnished under such a contract is of vital important. These cannot be written casually but must represent the best experience in the field on the subject and should be prepared only by or under the direction of those who have had actual and repeated operational experience under extreme cold conditions.
Properly prepared specifications should not only specify detailed design information or criteria for the equipment but should describe fully the use to which the equipment will be put, the extreme and average conditions under which it will operate, and the difficulties that may be anticipated, citing problems that may be expected and that may have arisen and have not yet been

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solved. Such added information will assume proper design and performance and avoid the possibility of over design which ofttimes results from lack of proper information or understanding of the problem.
Specifications for other than proved equipment should include testing under the conditions established in the design criteria and should provide for corrective measures to produce the specified or desired equipment. New equipment, once committed to arctic operations, should be followed carefully and reports on such equipment should be returned to the originator of the specification. Such experience will tend to provide the needed balance in design which will ultimately result in providing the equipment most suitable for use under year-round arctic conditions.

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BIBLIOGRAPHY

1. American Society for Metals. Metals Handbook . Cleveland, O., 1948.

2. Battelle Memorial Institute, Columbus. Low Temperature Properties of Lead-Base Solders and Soldered Joints . December, 1948. Laboratory publication No.198-48.

3. Smith, C.S. “Mechanical properties of copper and its alloys at low temperatures,” Am.Soc.Test.Mat., Proc ., 1939, vol.39, pp.642-48.

4. Stefansson, Vilhjalmur. Arctic Manual . N.Y., Macmillan, 1944.

5. U.S. Forest Service. Forest Products Laboratory, Madison, Wis. Survey of Available Literature on the Effect of Arctic Exposure Conditions on the Strength Properties of Wood . Madison, Wis., June 4, 1948.

Palmer W. Roberts
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